富馬酸是一種羧酸。如果存在堿，則羧酸會(huì)釋放氫離子。它們以這種方式與所有堿（有機(jī)（例如胺）和無(wú)機(jī)堿）反應(yīng)。它們與堿的反應(yīng)，稱(chēng)為“中和”，伴隨著大量熱量的釋放。酸和堿之間的中和產(chǎn)生水加鹽。具有六個(gè)或更少碳原子的羧酸可自由或中度溶于水；碳原子數(shù)超過(guò)6的化合物微溶于水。水溶性羧酸在水中解離一定程度以產(chǎn)生氫離子。因此，羧酸溶液的pH小于7.0。許多不溶性羧酸與含有化學(xué)堿的水溶液迅速反應(yīng)，并隨著中和生成可溶鹽而溶解。
Fumaric acid is a carboxylic acid. If a base is present, the carboxylic acid releases hydrogen ions. In this way they react with all bases (organic (e.g., amines) and inorganic bases. Their reaction with alkali, called neutralization, is accompanied by the release of a large amount of heat. Neutralization between acid and alkali produces water and salt. Carboxylic acids with six or fewer carbon atoms are free or moderately soluble in water; compounds with more than six carbon atoms are slightly soluble in water. Water soluble carboxylic acids dissociate to a certain extent in water to produce hydrogen ions. Therefore, the pH value of carboxylic acid solution is less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing chemical bases, and dissolve with neutralization to form soluble salts.
水溶液中的羧酸和液體或熔融羧酸可與活性金屬反應(yīng)形成氣態(tài)氫和金屬鹽。這樣的反應(yīng)原則上也對(duì)固體羧酸發(fā)生，但是如果固體酸保持干燥，則反應(yīng)會(huì)緩慢。甚“不溶”羧酸也可能從空氣中吸收足夠的水，并在其中充分溶解，從而腐蝕或溶解鐵，鋼和鋁的零件和容器。羧酸與其他酸一樣，與氰化物鹽反應(yīng)生成氣態(tài)氰化氫。對(duì)于干燥的固體羧酸，反應(yīng)較慢。不溶性羧酸與氰化物溶液反應(yīng)，導(dǎo)致釋放出氣態(tài)氰化氫。
Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and metal salts. In principle, this reaction also occurs for solid carboxylic acids, but if the solid acids are kept dry, the reaction will be slow. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve them sufficiently to corrode or dissolve iron, steel and aluminum parts and containers. Carboxylic acid, like other acids, reacts with cyanide salts to form gaseous hydrogen cyanide. For dry solid carboxylic acids, the reaction is slow. The insoluble carboxylic acid reacts with cyanide solution, resulting in the release of gaseous hydrogen cyanide.
羧酸與重氮化合物，二硫代氨基甲酸酯，異氰酸酯，硫醇，氮化物和硫化物的反應(yīng)會(huì)產(chǎn)生易燃或有毒氣體和熱量。羧酸，尤其是水溶液中的羧酸，還會(huì)與亞硫酸鹽，亞硝酸鹽，硫代硫酸鹽（生成H2S和SO3），連二亞硫酸鹽（SO2）反應(yīng)，生成易燃或有毒氣體和熱量。它們與碳酸鹽和碳酸氫鹽的反應(yīng)生成無(wú)害氣體（二氧化碳），但仍會(huì)發(fā)熱。
The reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides and sulfides can produce flammable or toxic gases and heat. Carboxylic acids, especially carboxylic acids in aqueous solutions, react with sulfites, nitrites, thiosulphates (to form H2S and SO3), and dithionite (SO2) to produce flammable or toxic gases and heat. They react with carbonates and bicarbonates to produce a harmless gas (carbon dioxide), but still generate heat.
像其他有機(jī)化合物一樣，羧酸可被強(qiáng)氧化劑氧化，并被強(qiáng)還原劑還原。這些反應(yīng)會(huì)產(chǎn)生熱量。各種各樣的產(chǎn)品都是可能的。像其他酸一樣 羧酸可引發(fā)聚合反應(yīng)；像其他酸一樣，它們經(jīng)常催化（增加反應(yīng)速率）。在446°（開(kāi)放容器）下發(fā)生部分碳化和馬來(lái)酸酐的形成。
Like other organic compounds, carboxylic acids can be oxidized by strong oxidants and reduced by strong reducing agents. These reactions produce heat. All kinds of products are possible. Like other acids, carboxylic acids initiate polymerization; like other acids, they often catalyze. Partial carbonization and maleic anhydride formation occurred at 446 ° in an open container.
